Ryan Campbell of Particletree offers a step-by-step guide to getting started with JSON. Since JavaScript can use JSON to either send or receive from the server (both parts of an AJAX request), Ryan suggests getting started with sending JSON (after stringifying it) to the server and converting it to a server side object. Then sending that object back, encoded as JSON, to the client and process that. He offers working library code for both JavaScript and PHP (for the server part).
Douglas Crockford's presentation on Advanced JavaScript. He covers topics such as inheritance, modules, debugging, efficiency and JSON.
Matt Kruse's JavaScript Toolbox presents a number of excellent best practice ideas including: using var, feature detection, when to use square bracket notation, avoiding eval, referencing forms and form elements, avoiding the with keyword, using onclick instead of JavaScript pseudo-protocol, using unary + to type convert to numbers, avoiding document.all, not using HTML comments in script blocks, avoid cluttering the global namespace, avoiding prototype.js, avoiding synch Ajax calls, using JSON and the correct way to use script tags